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![[tex]1)[/tex]](images/latex/320dfa19ec73b5e4b004165c8fa3ba9407055bce_0.png "[tex]1)[/tex]")
![[tex]Q(+) \quad W\sim0 \quad \Delta U(-) \quad \Delta H(+) \quad \Delta S(-) \quad \Delta G=0 \quad \Delta A=0 [/tex]](images/latex/16452283e65258bb2d1afa07e28d75b0a59e555e_0.png "[tex]Q(+) \quad W\sim0 \quad \Delta U(-) \quad \Delta H(+) \quad \Delta S(-) \quad \Delta G=0 \quad \Delta A=0 [/tex]")
![[tex]Q=0 \quad W(-) \quad \Delta U(-) \quad \Delta H(-) \quad \Delta S=0[/tex]](images/latex/d1efdd3caef5d061cade8babc766dddc09031ec2_0.png "[tex]Q=0 \quad W(-) \quad \Delta U(-) \quad \Delta H(-) \quad \Delta S=0[/tex]")
![[tex]Q(-) \quad W(+) \quad \Delta U=0 \quad \Delta H=0 \quad \Delta S(-) \quad \Delta G(+) \quad \Delta A(+) [/tex]](images/latex/a1f6aebc3afda9e3081f6c35252ae725205ebedd_0.png "[tex]Q(-) \quad W(+) \quad \Delta U=0 \quad \Delta H=0 \quad \Delta S(-) \quad \Delta G(+) \quad \Delta A(+) [/tex]")
![[tex]Q(-) \quad W=0 \quad \Delta U(-) \quad \Delta H(-) \quad \Delta S(-) [/tex]](images/latex/14338f06ada8841eef98896eb187c1d1597c5374_0.png "[tex]Q(-) \quad W=0 \quad \Delta U(-) \quad \Delta H(-) \quad \Delta S(-) [/tex]")
![[tex]C_{12}H_{22}O_{11}(s)+12O_{2}(g)\longrightarrow12CO_{2}(g)+11H_{2}O(l)[/tex]](images/latex/55f600ebea4bd4786bb9c89acafcb3396ca6fb31_0.png "[tex]C_{12}H_{22}O_{11}(s)+12O_{2}(g)\longrightarrow12CO_{2}(g)+11H_{2}O(l)[/tex]")
![[tex]Q_{v}=\Delta U=-2082J[/tex]](images/latex/cdf957935bb8a511e28a4e7c752aa5e1cdf1fb4b_0.png "[tex]Q_{v}=\Delta U=-2082J[/tex]")
![[tex] \Delta H_{RQ} = \Delta U_{RQ} + RT \Delta n_{g}[/tex]](images/latex/c4421420956c771ec2af12e040d92961b49ec285_0.png "[tex] \Delta H_{RQ} = \Delta U_{RQ} + RT \Delta n_{g}[/tex]")
![[tex]Si \ \Delta n_{g}=0 \Longrightarrow \Delta H_{RQ}=\Delta U_{RQ}[/tex]](images/latex/49c7dd7be05748ce7f605baed8cebab735213bb5_0.png "[tex]Si \ \Delta n_{g}=0 \Longrightarrow \Delta H_{RQ}=\Delta U_{RQ}[/tex]")
![[tex]3)[/tex]](images/latex/763918841fe812c236a2349d66f3505e812a9909_0.png "[tex]3)[/tex]")
![[tex]\Delta H_{T}=377760-10.55T[/tex]](images/latex/5985c14ebd19c18c5c2e1ab88d9f603d2531a4be_0.png "[tex]\Delta H_{T}=377760-10.55T[/tex]")
![[tex] \frac{\Delta H_{T}}{RT^{2}}= \frac {45434}{T^{2}} - \frac {1.269}{T}= \frac {\partial ln P}{ \partial T}[/tex]](images/latex/b40439c98a3163d1c1313179d747190fa1e9f74a_0.png "[tex] \frac{\Delta H_{T}}{RT^{2}}= \frac {45434}{T^{2}} - \frac {1.269}{T}= \frac {\partial ln P}{ \partial T}[/tex]")
![[tex] ln \ P^{o}_{Fe(l)}[atm] = - \frac {45434}{T} - 1.269 lnT + 23.94[/tex]](images/latex/29a6313107af34f60590c754ab4933c215322c09_0.png "[tex] ln \ P^{o}_{Fe(l)}[atm] = - \frac {45434}{T} - 1.269 lnT + 23.94[/tex]")
![[tex]4) [/tex]](images/latex/9f4a40a327fc3edd23bf07b74307f56390f3412a_0.png "[tex]4) [/tex]")
![[tex]K_{b} = \frac{[NH_{4}^{+}][OH^{-}]}{[NH_{3}]}[/tex]](images/latex/bf69edb8a515fae966ff774240b575dcf03074ab_0.png "[tex]K_{b} = \frac{[NH_{4}^{+}][OH^{-}]}{[NH_{3}]}[/tex]")
![[tex]K_{w} = [OH^{-}][H^{+}][/tex]](images/latex/ab2251079c243fce51417730261f6c8b2c64fc93_0.png "[tex]K_{w} = [OH^{-}][H^{+}][/tex]")
![[tex]C_{NH3}^{o}= [NH4^{+}]+[NH3][/tex]](images/latex/85bfeced85b4f5233236ca5f8ddc267f5d6c7d69_0.png "[tex]C_{NH3}^{o}= [NH4^{+}]+[NH3][/tex]")
![[tex]C_{HCl}^{o}= [Cl^{-}][/tex]](images/latex/42f0aaead483f4784bd52eb82526834ae21d7075_0.png "[tex]C_{HCl}^{o}= [Cl^{-}][/tex]")
![[tex][H^{+}]+[NH4^{+}]=[OH^{-}]+[Cl^{-}][/tex]](images/latex/bd3dd1f44ebb7c86303f37fe879c1792c0c9e3f9_0.png "[tex][H^{+}]+[NH4^{+}]=[OH^{-}]+[Cl^{-}][/tex]")
![[tex][OH^{-}] y [H^{+}][/tex]](images/latex/9bb2f950b68f12fd09ace784c83d515801751951_0.png "[tex][OH^{-}] y [H^{+}][/tex]")
en BQ
![[tex]C_{HCl}^{o}= [Cl^{-}]= [NH4^{+}][/tex]](images/latex/961166d99ec7fdb40ac301d582269eb9fc1898d6_0.png "[tex]C_{HCl}^{o}= [Cl^{-}]= [NH4^{+}][/tex]")
![[tex][NH3]=C_{NH3}^{o}-[NH4^{+}]= C_{NH3}-C_{HCl}[/tex]](images/latex/9df836b4f1d3b0372e704749f6603080c5d8c068_0.png "[tex][NH3]=C_{NH3}^{o}-[NH4^{+}]= C_{NH3}-C_{HCl}[/tex]")
![[tex]Kb= \frac{C_{HCl}^{o}[OH^{-}]}{C_{NH3}-C_{HCl}} \Longrightarrow \frac{C_{NH3}}{C_{HCl}}=6.6[/tex]](images/latex/346bc760a5fdea247c0d01131e635a646f284cda_0.png "[tex]Kb= \frac{C_{HCl}^{o}[OH^{-}]}{C_{NH3}-C_{HCl}} \Longrightarrow \frac{C_{NH3}}{C_{HCl}}=6.6[/tex]")
![[tex]C_{NH3}[/tex]](images/latex/59bd89740bd8ba8cdb5be77a7369584a69112edf_0.png "[tex]C_{NH3}[/tex]")
y ![[tex]C_{HCl}[/tex]](images/latex/269e7fa70981de52a6a35467dfeea46871f9e977_0.png "[tex]C_{HCl}[/tex]")
![[tex]K_{ps}=[Ca^{2+}][F^{-}]^{2}[/tex]](images/latex/fd8a022b36397627811ad4cbcfc39066df4baf06_0.png "[tex]K_{ps}=[Ca^{2+}][F^{-}]^{2}[/tex]")
![[tex]K_{a}=\frac{[H^{+}][F^{-}]}{[HF]}[/tex]](images/latex/0298eb0062fe0337b3a88a61b40dcfa1640d47bf_0.png "[tex]K_{a}=\frac{[H^{+}][F^{-}]}{[HF]}[/tex]")
![[tex]S=[Ca^{2+}][/tex]](images/latex/d1d3841f6bf09977e8a998f1ea9e69cd6210b9dd_0.png "[tex]S=[Ca^{2+}][/tex]")
![[tex]2S=[F^{-}]+[HF][/tex]](images/latex/88e77f4831212a3f20a6b0a747f736d22310f4a9_0.png "[tex]2S=[F^{-}]+[HF][/tex]")
![[tex]S=\sqrt[3]{ \frac{K_{ps}}{4}\bigg\{ 1+ \frac{[H^{+}]}{K_{a}}\bigg\}^{2}}[/tex]](images/latex/6805606fed9eb7ebd99d283b3216fc0502df661d_0.png "[tex]S=\sqrt[3]{ \frac{K_{ps}}{4}\bigg\{ 1+ \frac{[H^{+}]}{K_{a}}\bigg\}^{2}}[/tex]")
![[tex]pH=10 \Longrightarrow S=2,15.10^{-4}M[/tex]](images/latex/725887f5664d73c5c4d11c91489513f10d7907bf_0.png "[tex]pH=10 \Longrightarrow S=2,15.10^{-4}M[/tex]")
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